B. Speiser, A. Rieker, S. Pons
Dec 9, 1983
Citations
0
Influential Citations
14
Citations
Journal
Journal of Electroanalytical Chemistry
Abstract
Abstract The electrochemical oxidation of 2,6-di- tert -butyl-4-R-anilines (R=C 6 H 5 , p -CH 3 O−C 6 H 4 and p -(CH 3)2 N−C 6 H 4 ) at the potentials of the second peak has been investigated. Dications could be observed and characterized by electroanalytical and spectroelectrochemical means. The cyclic voltammogram of the methoxy compound has been simulated by the orthogonal collocation method. Products of bulk electrolysis have been identified. We found two different sites of nucleophilic attack in the case of the methoxy compound.