S. Torii*, Hideo Tanaka, Kiyosi Misima
May 1, 1978
Citations
0
Influential Citations
7
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Bis(dialkylthiocarbamoyl) disulfides were synthesized directly from dialkylamines and carbon disulfide by electrolysis under constant voltage using an undivided cell. The electrochemical reaction was carried out effectively in a two-layer system of electrolysis solvents, e. g., water–chloroform, water–dichloromethane, water–1,2-dichloroethane, and water–carbon disulfide. Likewise, the electrolysis could be performed in a homogeneous solution using dimethylformamide and/or acetonitrile.