L. Gânscă, A. Gocan, I. Oprean
Dec 31, 2002
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Journal
ChemInform
Abstract
The synthesis of the four isomers of 4,7-tridecadien-1-yl acetate, based on a C 5 +C 8 scheme is described. The coupling reaction took place between the Grignard reagent of pent-4-yn-1-oic acid and 1-bromo-2(Z/E)-octene. The four isomers were separated on SiO 2 -AgNO 3 TLC plate and GS-MS. (4E,7Z)-4,7-Tridecadien-1-yl acetate is the sex pheromone of the spottet tentiform leafminer moth Phylonorycter corylifoliella.