Liu Wei-xiao
2009
Citations
0
Influential Citations
0
Citations
Journal
Chinese Journal of Explosives and Propellants
Abstract
Taking 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione as primary material,1,3,5-tris(2-nitroethyl)-1,3,5-triazinane-2,4,6-trione(TNEIC) and 1,3,5-tris(2-azidoethyl)-1,3,5-triazinane-2,4,6-trione(TAEIC) were synthesized via nitration and azidonation.The optimum conditions of nitration were:HNO3/H2SO4(volume ratio),1∶1;reaction temperature,25℃;reaction time,0.25h and the optimum reaction yield is 92.0%.The structure of the final product was confirmed by IR,1 HNMR,and elemental analysis.The thermal properties of the compounds were determined by DSC and TG.The results show that TAEIC has a low melting point and will be used in melt-cast explosive.