F. Helzy, Thierry Maris, J. Wuest
Apr 11, 2008
Citations
0
Influential Citations
20
Citations
Journal
Crystal Growth & Design
Abstract
In 6,6′,6′′-(1,3,5-phenylene)tris-1,3,5-triazine-2,4-diamine, three trigonally directed diaminotriazinyl groups are attached to the 1,3,5-positions of a phenyl core. This introduces a significant capacity for intermolecular hydrogen bonding, because each diaminotriazinyl group can normally interact with two others to form a total of four hydrogen bonds. Derivatives 3 and 4, which have alkyl groups at the 2,4,6-positions, are designed to favor a conformation in which the diaminotriazinyl groups are held perpendicular to the phenyl core. This conformation is expected to direct the hydrogen bonding of each diaminotriazinyl group out of the plane of the phenyl core, leading to generation of a three-dimensional (3D) network in which each molecule is linked to six neighbors by a total of 12 hydrogen bonds. In fact, the observed networks all show a lower degree of connectivity, possibly because the cores of compounds 3 and 4 are too compact to accommodate six fully hydrogen-bonded neighbors. Nevertheless, compou...