Yifan Yang, Qing Zheng, Yuanyuan Yan
2018
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Journal
Chinese Chemical Letters
Abstract
Abstract This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH 2 OH) molecular clusters. The enhanced electronic communication in FcCH 2 OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivatives which is based on the intermolecular hydrogen-bonding.