Haixian Ren, F. Huo, Yongfei Huang
Oct 1, 2020
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Influential Citations
14
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Journal
Dyes and Pigments
Abstract
Abstract Thiophenols are an important class of raw material and intermediate to prepare pesticides, medicines and polymers in chemical industry. However, they are highly toxic and harmful to the organisms and the environment, evaluated as No. P014 acute hazardous waste by USEPA (the environmental protection agency in US). Despite establishing the permittable discharge standards, thiophenols still bring about a threat to the environment primarily due to the absence of reliable and convenient detection methods. In this study, 2,4-dinitrobenzenesulfonyl (DNPS) was introduced to enhance SNAr, then ESIPT of the fluorophore was triggered quickly by ‘enhanced SNAr’ between the probe and strongly nucleophilic thiophenols, thus NIR ultrafast thiophenols detection was realized. The probe was able to detect the 4-methyl thiophenol (MTP) within 13 s with the limit of detection (LOD) of 13.3 nM (below the exposure limit of 0.5 ppm provided by the National Institute for Occupational Safety and Health (NIOSH)). More, the probe was successfully applied to monitor the levels of the thiophenols in environmental water samples and Hela cells.