U. Bhardwaj, S. Maken, K. C. Singh
Jan 15, 1998
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Journal
Fluid Phase Equilibria
Abstract
Abstract Excess molar enthalpies at 308.15 K are reported for 2-methylpropan-1-ol with benzene, toluene, o-, m- and p-xylene over the entire range of composition. The analysis in terms of an athermal associated mixture model (Mecke–Kempter type) with a Flory contribution term and quasi-chemical model by Barker is described. Association model predicts good agreement with VE data, while the prediction of both association model and quasi-chemical model are fairly good for HE data.