Wang Shi-ming
2004
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Journal
Fine Chemical Intermediates
Abstract
The etherification of isoamylenes and methanol to form tert ayl methyl ether (TAME) by benzl-sulfonic acid cation exchange resin as catalyst, was sudied. The influences of temperature, methanol/isoamylenes ratio and LHSV have been investigated. The results indicats that the resin is an effective catalyst with conversion over 70% at 59~67?℃ and n(methanol)∶n(isoamylenes)=1.4~1.6∶1.0,LHSV=1.1~1.5.