K. Fromm, E. Gueneau, J. Rivera
2002
Citations
0
Influential Citations
18
Citations
Journal
Zeitschrift für anorganische und allgemeine Chemie
Abstract
Dibenzo-18-crown-6 was chosen as ideal ligand for the complexation of a sodium cation in the aim to allow further coordination of iodide and another oxygen donor ligand in order to generate an asymmetric coordination sphere. The crystal structures obtained with NaI with this ligand and second one with a larger cavity are presented, forming molecular units, and featuring interesting physical properties such as optical birefringence dispersion.