M. Tulp, O. Hutzinger
Sep 11, 1977
Citations
0
Influential Citations
9
Citations
Journal
Journal of chromatography
Abstract
The mass spectra and gas chromatographic properties of a number of chlorobiphenylols, chlorobiphenyldiols, chlorophenols and naphthols, as well as their methyl, deuteriomethyl and ethyl ethers and some cyclic n-butylboronates have been investigated. Metabolism experiments with 4'-chloro-4-biphenylol showed that the selective use of ethylation and methylation is most effective in both detection and structure elucidation of metabolites partly methylated by metabolic processes. The usefulness of deuteriomethylation in such studies seems to be limited. The formation of cyclic n-butylboronates provides specific information on o-dihydroxy derivatives of chlorobiphenyls.