T. Bailly, R. Burgada
Apr 1, 1995
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Journal
Phosphorus Sulfur and Silicon and The Related Elements
Abstract
Abstract The Kabachnik-Fields and Moedritzer-lrani reactions are studied in the case of 1-2 diamino trans cyclohexane dl as aminated component. The new bicyclic bis phosphonates 1, 1′, la have been obtained in the first case and the tetra phosphonic acid 2′ in the second one. The methylene bridge between the two nitrogen atoms in 1 and la is a protecting group that is stable in basic medium and readily removed at 20°C in acidic conditions. The 1H, 31C and 31P spectra are reported for all new compounds.