A. A. Macharashvili, V. Shklover, Y. Struchkov
Nov 15, 1988
Citations
0
Influential Citations
22
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract An X-ray study of chloro[1-{1,1-dimethyl-2-(4′methoxybenzoyl)hydrazonium} methyl]dimethylsilane (I) has been carried out ( R = 0.035 for 2800 reflections). The Si atom, which has a trigonal-bipyramidal [4 + 1] coordination with the O and Cl atoms in axial positions (Si–O 1.788(1) A, SiCl 2.624(1) A, is markedly displaced from the equatorial plane towards the oxygen atom (Δ Si 0.178 A), which confirms that there is a coordinate bond between the silicon atom and chloride ion.