L. G. Golubyatnikova, G. R. Anpilogova, R. A. Khisamutdinov
Mar 15, 2012
Citations
0
Influential Citations
10
Citations
Journal
Russian Journal of General Chemistry
Abstract
Extraction of hydrochloric and nitric acid with 1-{[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]-methyl}-1H-1,2,4-triazole (propiconazole) and hydrochloric acid with (RS)-1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-yl-methyl)-pentan-3-ol (tebuconazole) was studied. It is established that extraction of acids proceeds with the formation of monosolvates as an exothermic process. Effective extraction constants of acids are evaluated. By means of the IR and 1H NMR spectroscopy it was shown that the protonaccepting center of tebuconazole is N4 atom of the triazole ring.