W. Chiou, Gau-Hong Lin, Chi-Wei Liang
Feb 8, 2010
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0
Influential Citations
24
Citations
Journal
The Journal of organic chemistry
Abstract
Facile syntheses of enantiopure trans- and cis-3-hydroxypiperidine derivatives and 3-hydroxypipecolic acids are reported, featuring Rh-catalyzed cyclohydrocarbonylation through common intermediates. A diaxial conformation in a 2,3-disubstituted N-Boc-piperidinyl structure is revealed by an X-ray crystallographic analysis.