Chen Haonan, Zou Yuanhai, Jianmin Zhang
Sep 2, 2014
Citations
0
Influential Citations
4
Citations
Journal
Tetrahedron
Abstract
Abstract A series of fluorinated fullerene-fused 1,3-dioxolanes have been facilely and efficiently synthesized in the presence of easily available LiClO 4 ·3H 2 O. The influences of the number of fluoro-substituents and their positions linked to the phenyl ring on the isolated yield of fullerene-fused 1,3-dioxolanes have been studied in detail. Based on reaction facts, a possible reaction mechanism for the formation of fluorinated fullerene-fused 1,3-dioxolanes has been proposed. Furthermore, detailed ultraviolet absorption spectra, fluorescence emission spectra, and cyclic voltammogram further explain the optical properties and electronic transmission capabilities of the products.