M. Shimizu, T. Hata, T. Hiyama
Oct 8, 1999
Citations
0
Influential Citations
13
Citations
Journal
Tetrahedron Letters
Abstract
Abstract Reaction of fluorotris(trimethylsilyl)methane and aldehydes is catalyzed by KF/18-Cr-6 to give 1,3-disubstituted 2-fluoro-2-propen-1-ols in one pot. On the other hand, SnLi exchange of bis(trimethylsilyl)-fluoro(tributylstannyl)methane with BuLi and subsequent treatment with an aldehyde afforded 1-fluoroalkenyltrimethylsilanes in moderate to good yields.