E. Dumez, Jean Rodriguez, J. Dulcere
1999
Citations
0
Influential Citations
6
Citations
Journal
Chemical Communications
Abstract
Allylic nitro compounds 1a–d undergo [2,3]-sigmatropic rearrangement in refluxing 1,2,4-trichlorobenzene, to afford rearranged alcohols 3a–d and carbonyl compounds 4a–d; the heating, under the same conditions, of a mixture of nitroalkenes 7a–c, propargyl alcohols or amine 8 and ButOK promotes a one-pot formation of allylic alcohols 3a–c.