C. Chai, G. Heath, P. Huleatt
1999
Citations
0
Influential Citations
9
Citations
Journal
Journal of The Chemical Society-perkin Transactions 1
Abstract
Polarographic stufies of 3,6-epidithiopiperazine-2,5-diones (ETP) including naturally occurring gliotoxin and simple synyhetic analogues are pertinent to understanding their biological action; coulometric measurements on 1,4-diethyl ETP in acetonitrille establish the existance of a ready one-electron reduction overall, in sharp contrast to the familiar two-electron cleavage of acyclic disulfides.