U. Schubert
Sep 23, 1980
Citations
0
Influential Citations
5
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract 9-Fluorenyltris(trimethylsilyl)silane (A) reacts with chlorine in CCl 4 to give dichloro-9-fluorenyltrimethylsilylsilane (B) in good yield. B is characterized spectroscopically and by X-ray structure analysis; it crystallizes in the triclinic space group P 1 with a 950(2), b 1367(3), c 1138(2) pm, α 137.5(1), β 109.9(2), γ 89.8(2)°. The conformation of B is staggered with approximate C s -symmetry; C(9)Si 187.6(5), SiSi 233.2(4), SiCl 207.1(3) and 205.3(3) pm.