H. Chiu, Yi Pin Chen, S. Chuang
1996
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0
Influential Citations
19
Citations
Journal
Chemical Communications
Abstract
Mononuclear nitrido complexes of Cr and Mo, NCr(OBut)3 and NMo(OSiMe3)3(py), are synthesized; the chromium complex has an idealized C3ν symmetry while the molybdenum complex has a distorted square-pyramidal geometry with the nitrido ligand at apical position; the N–Cr distance is 1.538(5)A while the average N–Mo distance is 1.627 A.