Guan‐Wu Wang, Jie Gao
Jun 4, 2009
Citations
1
Influential Citations
74
Citations
Quality indicators
Journal
Organic letters
Abstract
An efficient methodology for the oxidative addition reaction of various aldehydes with 5,5-dimethylcyclohexane-1,3-dione and 1,3-indandione to selectively afford spiro dihydrofuran and cyclopropane derivatives, promoted by molecular iodine and dimethylaminopyridine under mechanical milling conditions, has been demonstrated. The products were obtained in good to excellent yields. A possible mechanism of this unusual reaction process is proposed.