I. Korhonen
1983
Citations
0
Influential Citations
10
Citations
Journal
Journal of Chromatography A
Abstract
Abstract The gas chromatography of 2-propen-1-ol, 2-propyn-1-ol, 3-buten-1-ol, 4-penten-2-ol, 4-penten-1-ol and trans -, and cis -3-hexen-1-ol and their propanoyl, 2- and 3-chloropropanoyl, butanoyl and 2-, 3- and 4-chlorobutanoyl derivatives has been studied on SE-30 and OV-351 capillary columns with programmed temperature rise. The alcohols and their esters are eluted in the same order on both non-polar and polar columns, whereas quite different elution orders of the individual components in mixtures of the alcohols and their C 3 - and C 4 -derivatives are observed on the columns used. In this respect 2-propyn-1-ol and its esters are the most diverging compounds, the alcohol having a retention time on OV-351 of over three times that on SE-30. Retention data for 56 compounds are given and the results are compared with those reported previously for the saturated alcohols and their derivatives.