I. Kind, T. Berndt, O. Böge
Jan 26, 1996
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Influential Citations
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Journal
Chemical Physics Letters
Abstract
Abstract The gas-phase reaction of NO 3 radicals with selected oxiranes has been studied in a flow system at T = 295 ± 2 K in the pressure range 3.4–50 mbar musing N 2 as carrier gas. The analysis of the organics was performed by means of on-line connected GC-FID. Rate constantswere obtained with the relative rate method: 3,4-epoxy-cyclohexene: (2.70 ± 0.18) × 10 −3 ; 2,2-dimethyl-vinyl)-oxirane; (4.74 ± 0.54) × 10 −12 ; 2-methyl-2-1(1-methyl-vinyl)-oxirane : (1.55 ± 0.12) × 10 −13 ; 2-methyl-2-vinyloxirane; (9.40 ± 2.62) × 10 −15 ; tetramethyloxirane: −15 ; and cis-2,3-dimethyloxirane: −15 cm −3 molecule −1 s −1 .