N. N. Zemlyansky, I. Borisova, M. G. Kuznetsova
Mar 18, 2003
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Organometallics
Abstract
New stable monomeric germanium(II) and tin(II) compounds M(OCH 2 CH 2 NMe 2 ) 2 (M = Ge (1); M = Sn (2)), stabilized by two intramolecular coordination M←N bonds and containing no bulky groups on the metal atoms, were synthesized. The molecular and crystal structures of these compounds, and that of the previously synthesized compound (ArO) 2 Sn (3; Ar = 2,4,6-(Me2NCH2)3C 6 H 2 ), were determined by X-ray diffraction analysis. The electronic structures of 1 and 2 were studied by the DFT method.