H. Sakurai, R. Kumai, A. Izuoka
Oct 1, 1996
Citations
1
Influential Citations
14
Citations
Journal
Chemistry Letters
Abstract
N,N-Dimethylamino nitronyl nitroxide (1) and its homologues were prepared. One-electron oxidation of these open-shell donors were fond to afford ground state triplet species based on the ESR spectroscopic measurements. The electronic structure of 1+• is characterized by the presence of the two singly occupied orbitals (SOMO and SOMO′) and can be regarded as a hetero-analogue of trimethylenemethane.