Songqi Ma, D. Webster, F. Jabeen
May 2, 2016
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Journal
Macromolecules
Abstract
A carboxylic acid functional trimer made from the reaction of isosorbide with maleic anhydride was used to cross-link epoxidized sucrose soyate (ESS), resulting in bio-based, degradable thermosets having a good combination of hardness and flexibility. This work addresses some critical needs for thermosets such as improving the sustainability of raw materials, enabling recycling, and achieving both good material hardness and flexibility/ductility simultaneously. In this paper, a dicarboxylic acid, MI, was synthesized from isosorbide and maleic anhydride and characterized in detail by FTIR and 1H NMR. It was utilized to cross-link ESS without using extra catalyst or toxic compounds except for ethanol and water. For comparison, a dicarboxylic acid from 1,3-propanediol and maleic anhydride (MP) was also synthesized and used to cross-link ESS. Because of the carbon–carbon double bond in conjugation with the carboxylic acid group, both MI and MP showed high reactivity toward ESS and could cross-link ESS with th...