Hazrat M. Noorzad, P. H. Gross
Dec 1, 1973
Citations
0
Influential Citations
6
Citations
Journal
Carbohydrate Research
Abstract
Abstract Benzyl 2-deoxy-α- d -gulopyranosido[2,3:4′,5′]-2′-oxazolidinone ( 10 ) was synthesized from benzyl 3- O -acetyl-2-[(benzyloxycarbonyl)amino]-2-deoxy-α- d -glucopyranoside ( 1 ) via the 4- O -methylsulfonyl-6- O -trityl derivative and 3,4-anhydro-α- d -galactopyranoside derivatives. Compound 10 and its 6- O -trityl and 4,6- O -benzylidene derivatives were permethylated with methyl iodide-barium oxide in N,N -dimethylformamide, the protective groups split off, and the resulting compounds acetylated to give the benzyl glycosides as well characterized, stable compounds that could be hydrolysed to give the title compounds.