R. V. Hes, U. Pandit, H. Huisman
Sep 2, 2010
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Journal
Recueil des Travaux Chimiques des Pays-Bas
Abstract
Reaction of vinylmagnesium bromide with quinolizidine-1-one yielded a mixture of two stereoisomeric 1-hydroxy-1-vinylquinolizidine systems (III and IV). Structural assignments of the latter are based upon infrared, nuclear magnetic resonance and mass spectral data. Attempts to transform the vinyl alcohols into 5-azasteroids were unsuccessful.