V. Zaitsev, D. Shabashov, O. Daugulis
Aug 31, 2005
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Journal
Journal of the American Chemical Society
Abstract
A new palladium-catalyzed arylation process based on C-H activation has been developed. The utilization of pyridine-containing directing groups allows the beta-arylation of carboxylic acid derivatives and gamma-arylation of amine derivatives. Both primary and secondary sp3 C-H bonds, as well as sp2 C-H bonds, are reactive.