S. Hashimoto*, N. Watanabe, S. Ikegami
1992
Citations
0
Influential Citations
35
Citations
Journal
Journal of The Chemical Society, Chemical Communications
Abstract
Rhodium(II) triphenylacetate, which features a bulky bridging ligand, has been demonstrated to exhibit an exceptionally high order of selectivity for aromatic C–H insertion over aliphatic C–H insertion or cyclopropanation in catalytic decompositions of α-diazocarbonyl compounds, thus providing an expedient and general entry to variously substituted indan-2-ones.