Kai A. I. Zhang, B. Tieke
Oct 2, 2008
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Journal
Macromolecules
Abstract
Synthesis and characteristic properties of polymers P-1−P-3 are described containing the 2,3,5,6-tetraarylated pyrrolo[3,4-c]pyrrole-1,4-dione unit in the main chain. P-1 is prepared from 2,5-bis(4-t-butylphenyl)-3,6-bis(4′-bromophenyl)pyrrolo[3,4-c]pyrrole-1,4-dione (DPP1) and 9,9-di-n-hexylfluorene-2,7′-bispinacolato-boronester 3, P-2 from 2,5-bis(4′-bromo-phenyl)-3,6-bis(4-t-butylphenyl)-pyrrolo[3,4-c]pyrrole-1,4-dione (DPP2) and 3, and P-3 from DPP1, 3, and 2,5-bis(n-hexyloxybenzene)-1,4-bispinacolatoboronester 4 via Pd-catalyzed Suzuki coupling. Molecular weights of the polymers are about 8000−10 000 Da. All polymers are soluble in common organic solvents such as toluene, chloroform, dichloromethane, tetrahydrofuran (THF), and dimethyl sulfoxide (DMSO) and exhibit a strong fluorescence with Stokes shift up to 56 nm (P-3) and quantum yield up to 81% (P-1). Although P-1 and P-2 are isomers, their optical and electrochemical properties are very different. P-1 with a polyconjugated carbon backbone exhibi...