Youqian Deng, Xin Jin, C. Fu
Apr 21, 2009
Citations
0
Influential Citations
30
Citations
Journal
Organic letters
Abstract
Highly regio- and stereoselective reactions of readily available 2-(methoxycarbonyl)-2,3-allenols 1 with oxalyl chloride in the presence of Et(3)N or DMSO afforded methyl 2-(ethynyl)alk-2(E)-enoates (E)-2 and 2-(1'-chlorovinyl)alk-2(Z)-enoates (Z)-3, respectively, in moderate to good yields.