C. C. H. Atienza, Aaron M. Tondreau, K. J. Weller
Sep 14, 2012
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111
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Quality indicators
Journal
ACS Catalysis
Abstract
Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4-trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires. The iron compounds exhibit unprecedented selectivity for the monohydrosilylation of the desired 4-alkene that far exceeds results obtained with commercially used platinum compounds.