Ya. A. Pankratova, Y. Nelyubina, V. Novikov
Jan 1, 2021
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Influential Citations
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Journal
Russian Journal of Coordination Chemistry
Abstract
Abstract The tetrahedral cobalt(II) complex [CoL 2 ](HNEt 3 ) 2 ( I ), where L is 1,2-bis(methanesulfonamido)benzene, exhibiting the properties of a single-molecule magnet is synthesized and characterized. The electronic structure parameters of complex I are determined by paramagnetic NMR spectroscopy. They completely reproduce the results of less available methods of studying single-molecule magnets. The value of axial anisotropy of the magnetic susceptibility estimated for complex I (Δχ ax = 34.5 × 10 –32 m 3 at 20°C) is record-breaking among all transition metal complexes studied by the NMR method, which provides wide possibilities for the use of complex I as a paramagnetic label for structural biology or as a contrast agent and even a temperature sensor for medical diagnostics. The data obtained indicate the advantages of paramagnetic NMR spectroscopy as a method of investigation of the magnetic properties and electronic structures of highly anisotropic transition metal complexes, which are precursors of many functional materials.