Yi-Wen Zheng, Bin Chen, Pan Ye
Aug 3, 2016
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Influential Citations
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Journal
Journal of the American Chemical Society
Abstract
We present a blueprint for aromatic C-H functionalization via a combination of photocatalysis and cobalt catalysis and describe the utility of this strategy for benzene amination and hydroxylation. Without any sacrificial oxidant, we could use the dual catalyst system to produce aniline directly from benzene and ammonia, and phenol from benzene and water, both with evolution of hydrogen gas under unusually mild conditions in excellent yields and selectivities.