Ahmed Abu-Rayyan, Qutaiba Abu-Salem, N. Kuhn
Mar 20, 2008
Citations
0
Influential Citations
5
Citations
Journal
Zeitschrift für anorganische und allgemeine Chemie
Abstract
On the Hydrolysis of 2,3-Dihydro-1,3-di-tert-butyl-4,5-dimethylimidazol-2-ylidene. The Crystal Structure of 1,3-Di-tert-butyl-4,5-dimethylimidazolium Bicarbonate 1,3-Di-tert-butyl-4,5-dimethylimidazolium bicarbonate (7), formed on the exposure of 2,3-dihydro-1,3-di-tert-butyl-4,5-dimethylimidazol-2-ylidene (6) towards air, is prepared on the reaction of 6 with ammonium bicarbonate; its crystal structure analysis reveals the presence of dimeric bicarbonate anions linked to each other and to the imidazolium ions with hydrogen bonds.