A. N. Fomina, B. Gostevskii, R. G. Mirskov
2002
Citations
0
Influential Citations
1
Citations
Journal
Russian Journal of General Chemistry
Abstract
Heating of dimethyl(2,2-dimethylhydrazino)silane and methylbis(2,2-dimethylhydrazino)silane with 1-hexene or styrene in the presence of a catalytic amount of rhodium dicarbonylacetylacetonate gives rise to adducts by the terminal carbon atom (yields 45-84%). The same reactions with phenylacetylene give complex mixtures of products formed primarily by disproportionation of the starting organosilicon reagents.