R. Danheiser, K. Romines, H. Koyama
Apr 28, 2003
Citations
0
Influential Citations
6
Citations
Journal
Organic Syntheses
Abstract
A hydroxymethyl anion equivalent: tributyl[(methoxymethoxy)methyl]stannane intermediate: (tributylstannyl)methanol reactant: Boron trifluoride etherate (13.0 mL, 0.106 mol) product: tributyl[(methoxymethoxy)methyl]stannane Keywords: addition, to CO; metalation reactions, tin; protection, oxygen; assay methods, for butyllithium, with 2-butanol, menthol, 2-pentanol, or 2-propanol, 1,10-phenanthroline indicator; boron trifluoride etherate; dichloromethane (methylene chloride); diisopropylamine; dimethoxymethane, purification; tetrahydrofuran; tributyltin hydride, preparation; organotin compounds, highly toxic; tin alkyls; tributyl[(methoxymethoxy)methyl]stannane, potential poison; (tributylstannyl)methanol, potential poison; flasks, alkaline washed