G. V. Malkov, A. Shastin, Y. Éstrin
Oct 1, 2010
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Influential Citations
3
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Journal
Macromolecular Symposia
Abstract
The results of the kinetic study of melt and solution polymerization at the 1,3-dipolar cycloaddition reaction of the AB 2 monomer - 2-azido-4,6-bis(prop-2-yn-1-yloxy)-[1,3,5]-triazine (ABPOT) are presented in this work as well as the results of the 13 C-NMR characterization of the obtained hyperbranched poly([1,2,3]-triazole-[1,3,5]-triazine)s. It is established, that the first-shell substitution effect during polyaddition process and unusual high degree of branching (up to 0.9) of polymers synthesized in melt are held.