T. V. Baukova, L. G. Kuzmina, A. Churakov
Dec 1, 1997
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Journal
Russian Chemical Bulletin
Abstract
A hypercoordinated 2,2′-diaurated 4-tert-butylbiphenyl derivative, which contains an intramolecular Au...Au secondary bond, was first synthesized by the reaction of 2,2′-dilithio-4-tert-butylbiphenyl with ClAuPPh3. The structure of the complex was established by X-ray structural analysis,1H and31P NMR spectroscopy, and fast-atom bombardment mass spectrometry.