N. PraveenGanesh, C. D. Candia, A. Memboeuf
Oct 15, 2010
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Influential Citations
7
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Journal
Journal of Organometallic Chemistry
Abstract
Vinylboronic esters derived from 4,4,6-trimethyl-[1,3,2]dioxaborinane react with nitrones in the presence of dimethylzinc; nucleophilic addition of the vinyl group onto nitrones produces N-allylic hydroxylamines in fair yields. The sequence is compatible with various functional groups on the vinylic moiety. The mechanism and kinetic aspects are discussed on the basis of DFT calculations.