M. Nierlich, Jean-Marc Sabattié, N. Keller
Jan 15, 1994
Citations
0
Influential Citations
9
Citations
Journal
Acta Crystallographica Section C-crystal Structure Communications
Abstract
The title complex, (1,4,7,10,13,16-hexaazacyclooctadecane)dioxouranium bis(trifluoromethylsulfonate), [UO 2 (C 12 H 30 N 6 )] 2+ .2CF 3 SO 3 - , is composed of [UO 2 (18-azacrown-6)] 2+ and CF 3 SO 3 - ions. In the cation, the uranyl is bonded to the six N atoms of the crown in a hexagonal bipyramidal coordination. This is the first reported uranyl hexaazacrown inclusion complex