Ivan Steels, P. Clercq, H. Maskill
1993
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0
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Journal
Journal of The Chemical Society, Chemical Communications
Abstract
Enforced intramolecular hydrogen bonding in 2-tert-butyl-3-(NN-dimethylamino)propan-1-ol is shown by the competitive alcoholysis of p-nitrophenyl acetate and 1-acetylimidazole in acetonitrile, and by the corresponding second-order rate constants and activation parameters, to influence both the rate and the mechanism of catalysed acyl transfer.