S. Vera, E. Rodenas
1986
Citations
1
Influential Citations
69
Citations
Journal
Tetrahedron
Abstract
Abstract The basic hydrolysis of 4-acetoxybenzoic acid and 2-naphtyl-acetate have been studied in cationic micelles of N-cetyl-N,N,N-tri-methylaamonium bromide and hydroxide and the results compared with the ones obtained for the basic hydrolysis of acetylsalicylic acid and 3-acetoxy-2-naphtoic acid. The results can be explained with the pseudo-phase kinetic Model and the determined second order rate constants in micelles are also smaller than the second order rate constants in water.