Stefan Pelties, A. Ehlers, R. Wolf
May 5, 2016
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0
Influential Citations
16
Citations
Journal
Chemical communications
Abstract
A new reaction mode for bicyclo[1.1.0]tetraphosphabutanes is reported. The C[double bond, length as m-dash]S and C[double bond, length as m-dash]N bonds of phenyl isothiocyanate reversibly insert into a P-P bond of [{CpNi(IMes)}2(μ-η(1):η(1)-P4)] (, IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene), forming isomers and . X-ray crystallography and (31)P{(1)H} NMR spectroscopy revealed similar bicyclo[3.1.0]heterohexane structures for these compounds.