Yiqiong Yang, Zenghui Zheng, Minhui Yang
Jun 3, 2020
Citations
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Influential Citations
91
Citations
Quality indicators
Journal
Journal of hazardous materials
Abstract
Perfluorooctanoic acid (PFOA), a widely used compound, is harmful to the environment and human health. In this study, a facile one pot solvothermal method of integrating BiOCl with Zn-Al hydrotalcite to form spherical-shaped BiOCl/Zn-Al hydrotalcite (B-BHZA) sample is reported. The characteristics and main factors affecting photocatalytic PFOA and photocatalytic mechanism of BiOCl/Zn-Al hydrotalcite (B-BHZA) are systematically investigated. It is found that spherical-shaped B-BHZA possesses abundant defects and a larger surface area of 64.4 m2 g-1. The factors affecting photocatalytic removal PFOA (e.g., time, pH, initial concentration and dosage) are investigated by modeling the 3D surface response. The removal rate of PFOA is over 90 % in 6 h under UV light at an optimal pH of 2, an initial concentration of 500 μg/L and a dose of dosage 0.5 g/L. The main mechanism occurs by photo-generated h+ oxidation and synergistic effects from the photocatalysis process. Though investigating the intermediates of PFOA degradation and F-, a possibility was proposed that h+ initiated the rapidly decarboxylation of PFOA. The unstable perfluoroheptyl group is formatted and further conversed to short chain perfluorocarboxylic acid. This study provides a new insight for the preparation of highly efficient photocatalysts to the treatment of halogenated compounds in UV system.