S. G. Mairanovskii, G. Bishimbaeva, N. Y. Grigor'eva
Dec 1, 1985
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Journal
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
Abstract
Conclusions1.The polarographic behavior of the four isomers of ethyl 3,7-diraethyl-10-oxo-2,6-decadienoate and also of model compounds (heptenal and 2E,6Z-farnesenic ester) was studied. During electroreduction intramolecular electron transfer from the ester groups to the aldehyde group occurs in the intermediately formed radical-anion.2.The existence of the conformation with closer aldehyde and carboxyl groups in the α,ω-aldehydo esters (I) was confirmed by the polarographic method.