Ikuo Sasaki, Tatsunosuke Amou, Hajime Ito
Mar 4, 2014
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0
Influential Citations
17
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Journal
Organic & biomolecular chemistry
Abstract
The development of an Ir-catalyzed ortho-C-H borylation of aromatic aldimines derived from pentafluoroaniline is reported. This reaction proceeded at 120 °C to afford the corresponding borylated products in high yield with good regioselectivity using an Ir complex formed in situ from [Ir(OMe)(cod)]2/2(C6F5)3P in the presence of 2-norbornene.