L. Freidlin, Yu. A. Kopyttsev, N. Nazarova
Aug 1, 1973
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Journal
Russian Chemical Bulletin
Abstract
1. The chloromethyl methyl sulfoxide complex of palladium catalyzes the hydrogenation and isomerization of 3-methyl-1-butene with the formation of a mixture of isopentenes. 2. The isomerization of 3-methyl-1-butene proceeds by theπ-allyl mechanism with the involvement of the hydride complex; 2-methyl-1-butene is formed directly from 3-methyl-1-butene, and not via a successive shift of the C=C bond.